https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:47170 Wed 14 Dec 2022 15:48:51 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38838 2H_H2O, δ¹⁸O_H2O, δ¹⁵N_NO3, δ¹⁸O_NO3 and δ¹³C_DIC) and radioactive (³H and ¹⁴C) isotopes were used in conjunction with three Contaminants of Emerging Concern (CECs) - carbamazepine, simazine and sulfamethoxazole - to discriminate between multiple potential contamination sources at an Australian WWTP. The radioactive isotope tritium provided a sensitive indicator of recent (post-1990s) leakage, with groundwater activities between 0.68 and 1.83 TU, suggesting WWTP infrastructure (activities between 1.65 and 2.41) acted as a recharge ‘window’, inputting treated or partially treated effluent to the underlying groundwater system. This was corroborated by water stable isotopes, which showed clear demarcation between δ¹⁸O_H2O and δ²H_H2O in background groundwater (δ¹⁸O_H2O and δ²H_H2O values of approximately −5 and −28‰, respectively) and those associated with on-site wastewater (median δ¹⁸O_H2O and δ²H_H2O values of −1.2 and −7.6‰, respectively), with groundwater down-gradient of the plant plotting on a mixing line between these values. The CECs, particularly the carbamazepine:simazine ratio, provided a means to further distinguish wastewater impacts from other sources, with groundwater down-gradient of the plant reporting elevated ratios (median of 0.98) compared to those up-gradient (median of 0.11). Distinctive CEC ratios in impacted groundwater close to the WWTP (∼3.0) and further down-gradient (2.7–9.3) are interpreted to represent a change in composition over time (i.e., recent vs. legacy contamination), consistent with the site development timeline and possible changes in effluent composition resulting from infrastructure upgrades over time. The data indicate a complex set of co-mingled plumes, reflecting different inputs (in terms of both quantity and concentration) over time. Our approach provides a means to better characterise the nature and timing of wastewater derived impacts on groundwater systems, with significant global implications for site management, potentially allowing more targeted monitoring, management and remedial actions to be undertaken.]]> Tue 15 Feb 2022 14:19:30 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:30338 Sat 24 Mar 2018 07:31:47 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38291 3-N, NH₄-N, Ca²⁺, SO₄^2-,HCO₃^- and K⁺ in conjunction with the other lines of evidence, allowed for enhanced separation between individual contaminant sources, particularly when paired with a detailed site history and Conceptual Site Model (CSM). This indicated that off-site agricultural impacts post-date most site derived impacts, and to date, have not significantly added to the identified contaminant plume. The outcomes of this work have significant global application in the identification, assessment, and control of environmental and health risks at complex sites and show how significant value (rarely obtained) can be derived from the analysis of routine monitoring datasets, particularly when analysed using a multiple lines of evidence approach.]]> Mon 23 Aug 2021 16:06:32 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38741 Fri 21 Jan 2022 09:04:04 AEDT ]]>